| SI.No. | Name | From | To |
| 1. | Shri Rajkishore Ray | 06.09.57 | 25.06.58 |
| 2. | Shri Gouri Kumar Brahma | 26.06.58 | 03.06.67 |
| 3. | Shri Kahnu Charan Mohanty | 04.06.67 | 23.03.68 |
| 4. | Dr. Binod Chandra Nayak | 08.04.68 | 02.09.73 |
| 5. | Shri Manoranjan Das | 16.11.74 | 15.01.80 |
| 6. | Shri Rai Charan Das | 15.04.80 | 23.03.83 |
| 7. | Shri Chintamani Behera | 31.03.83 | 16.08.85 |
| 8. | Shri Surendranath Satapathy | 12.09.85 | 30.06.90 |
| 9. | Shri Indu Bhusan Kar | 17.08.90 | 04.11.94 |
| 10. | Shri Raj Kishore Mishra | 05.12.94 | 30.09.96 |
| 11. | Dr. Haraprasad Paricha Patnaik | 01.10.96 | 19.09.99 |
| 12. | Shri Ashwini Kumar Mishra | 09.08.99 | 31.12.02 |
| 13. | Shri Rajkishor Mishra | 25.08.03 | 24.08.04 |
| 14. | Shri Chandra Sekhar Dasburma | 15.09.04 | 30.04.06 |
| 15. | Shri Rabindra Nath Das | 01.05.06 | 30.04.07 |
| 16. | Dr. Haraprasad Paricha Patnaik | 04.09.07 | 03.09.10 |
| 17. | Dr. Bijayananda Singh | 04.09.10 | 01.01.11 |
| 18. | Sri Bijaya Kumar Nayak | 01.01.11 | 22.08.14 |
| 19. | Sri Bishnu Prasad Mishra | 22.08.14 | 30.01.15 |
| 20. | Sri Aswini Kumar Mishra | 30.01.15 | 29.01.18 |
| 21. | Dr. Jayanti Rath | 02.02.18 | 31.01.20 |
| 22. | Smt. Suchismita Mantry | 01.02.20 | 27.05.2021 |
| 23. | Sri Prabodh Kumar Rout | 28.05.2021 | 18.07.2023 |
| 24. | Smt Suchismita Mantry | 24.07.2023 | 27.09.2023 |
| 25. | Sri Subodh Chandra Acharya | 27.09.2023 | -- |